Variation in the concentration of titanium in the sampling solutions as a function of the duration of the 50% biaxial deformations for nitrile (NBR) and butylrubber (IIR) samples exposed to nTiO2 powder and to colloidal solutions of nTiO2 [L. Vinches et al., Nanoscience Methods 2 (2013) 1-15].
No nanoparticle penetration was measured through butyl gloves, even after many hours ofdeformations. In the case of nitrile gloves, nanoparticles have penetrated after 7 h (nanoTiO2 powder) and 5 h (nanoTiO2 colloidal solution). The penetration of nanoparticles may be partly explained by the degradationof their physical and mechanical properties following repetitive mechanical deformations and contact with nanoTiO2 liquid carriers.